same issue here. On System Preferences > iCloud, iCloud Drive is selected but there is no option available for Desktop and Documents.
On System Preferences > Internet Accounts > iCloud, then iCloud Drive as the Options button. I selected Desktop & Documents Folders and it seems to work, icons have the cloud badge as if syncing. My old Desktop/Documents are not showing, if I go to iCloud.com/drive I can see my old files, but not the new ones.
mattiab
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