Same issues after upgrade to BigSure.
Can't save as .pdf in Word, nor print to pdf across Mac iOS, nor use my brother Hl5240 browser.
A reinstall of Office did'nt do it either.
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This fixed it for the pdfs for me: lifewire.com/reset-mac-printing-system-to-fix-os-x-printer-problems-2259970
Still need to connect my printer though :)