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It turns out that the entitlement approval process is two-stage, even though I can't find anything documenting that. The Certificates, Identifiers, & Profiles support people weren't helpful. I filed a TSI, and they told me I needed to submit the entitlement request form a second time. I did that (I put something in sponsor field about wanting Distribution access), and after a few hours I got another approval mail (identical to the original one I received). After that, my distribution profiles had the entitlement.